Injection
The injection
portion of the treatment program begins with the mobilization
of our equipment and personnel. Our equipment consists
of a treatment vehicle (about 28 ft to 40 ft). Typically GCI utilizes
one treatment specialist and sampling technician per
treatment vehicle on-site. All sites need to be equipped
with power and water, which can be supplied by GCI, if
necessary. Mobilization and set-up typically take about
1-day.
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Prior to commencement of injection,
GCI obtains a round of groundwater samples from all of the
injectors and monitoring wells on-site to establish site
wide baseline conditions. These samples are analyzed for
pH, alkalinity, iron, chloride, peroxide concentrations,
PID headspace, and temperature.
GCI will typically begin
the injection with a catalyst pre-treatment, followed by
a radius of influence study. GCI will then begin to simultaneously
inject oxidant and catalyst into the subsurface. Each treatment
vehicle is equipped to inject into 4 injection locations simultaneously.

GCI typically injects peroxide at concentrations between 3% and 12%, starting at lower
concentrations and increasing throughout the treatment program.
GCI will proportion the reagents throughout the injectors
on-site using three main determinants: ROI, baseline
contaminant mass, and PID headspace response. Initially,
GCI determines a volume of oxidant that needs to be added
to each injector in order to establish connectivity between
locations, then calculates a mass of contaminant and a
corresponding volume of oxidant needed to oxidize this
mass at each injector location. These two quantities are
compared and the higher of the two volumes is then assigned
to each injector location.

During the injection, injectors are sampled daily to monitor the progression of
the treatment program. GCI evaluates the peroxide distribution
on a daily basis using the PID headspace response ensuring
that reagents are delivered to areas on-site where treatment
is not yet complete. GCI employs a continuous injection
methodology in order to create and maintain optimal subsurface
oxidizing conditions.
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